Krypton

For other uses, see Krypton (disambiguation). bromine ← krypton → rubidium Ar ↑ Kr ↓ Xe 36Kr Periodic table Appearance colorless gas with whiteish emission General properties Name, symbol, number krypton, Kr, 36 Element category noble gases Group, period, block 18, 4, p Standard atomic weight 83.798 g·mol−1 Electron configuration Ar 3d10 4s2 4p6 Electrons per shell 2, 8, 18, 8 (Image) Physical properties Phase gas Density (0 °C, 101.325 kPa) 3.749 g/L Melting point 115.79 K, -157.36 °C, -251.25 °F Boiling point 119.93 K, -153.22 °C, -244.12 °F Triple point 115.775 K (-157°C), 73.2 kPa Critical point 209.41 K, 5.50 MPa Heat of fusion 1.64 kJ·mol−1 Heat of vaporization 9.08 kJ·mol−1 Specific heat capacity (25 °C) 20.786 J·mol−1·K−1 Vapor pressure P/Pa 1 10 100 1 k 10 k 100 k at T/K 59 65 74 120 Atomic properties Oxidation states 2 Electronegativity 3.00 (Pauling scale) Ionization energies 1st: 1350.8 kJ·mol−1 2nd: 2350.4 kJ·mol−1 3rd: 3565 kJ·mol−1 Covalent radius 116±4 pm Van der Waals radius 202 pm Miscellanea Crystal structure cubic face-centered Magnetic ordering diamagnetic1 Thermal conductivity (300 K) 9.43x10-3 W·m−1·K−1 Speed of sound (gas, 23 °C) 220, (liquid) 1120 m/s CAS registry number 7439-90-9 Most stable isotopes Main article: Isotopes of krypton iso NA half-life DM DE (MeV) DP 78Kr 0.35% 78Kr is stable with 42 neutrons 79Kr syn 35.04 h ε - 79Br β+ 0.604 79Br γ 0.26, 0.39, 0.60 - 80Kr 2.25% 80Kr is stable with 44 neutrons 81Kr trace 2.29×105 y ε - 81Br γ 0.281 - 82Kr 11.6% 82Kr is stable with 46 neutrons 83Kr 11.5% 83Kr is stable with 47 neutrons 84Kr 57% 84Kr is stable with 48 neutrons 85Kr syn 10.756 y β− 0.687 85Rb 86Kr 17.3% 86Kr is stable with 50 neutrons This box: view • talk •

Krypton (pronounced /ˈkrɪptɒn/, KRIP-ton; from Greek: kryptos "the hidden one") is a chemical element with the symbol Kr and atomic number 36. It is a member of Group 18 and Period 4 elements. A colorless, odorless, tasteless noble gas, krypton occurs in trace amounts in the atmosphere, is isolated by fractionally distilling liquified air, and is often used with other rare gases in fluorescent lamps. Krypton is inert for most practical purposes. Krypton can also form clathrates with water when atoms of it are trapped in a lattice of the water molecules.

Krypton, like the other noble gases, can be used in lighting and photography. Krypton light has a large number of spectral lines, and krypton's high light output in plasmas allows it to play an important role in many high-powered gas lasers, which pick out one of the many spectral lines to amplify. There is also a specific krypton fluoride laser. The high power and relative ease of operation of krypton discharge tubes caused (from 1960 to 1983) the official meter to be defined in terms of the orange spectral line of krypton-86.

Contents 1 Physical properties 2 History 2.1 Metric role 3 Occurrence 4 Compounds 5 Isotopes 6 Applications 7 Precautions 8 References 9 Further reading 10 External links // Physical properties 1×5 cm vial of glowing ultrapure krypton

Krypton is characterized by several sharp emission lines (spectral signatures) the strongest being green and yellow.2 It is one of the products of uranium fission.3 Solidified krypton is white and crystalline with a face-centered cubic crystal structure, which is a common property of all noble gases.

History

Krypton was discovered in Britain in 1898 by Sir William Ramsay, a Scottish chemist, and Morris Travers, an English chemist, in residue left from evaporating nearly all components of liquid air. Neon was discovered by a similar procedure by the same workers just a few weeks later.4 William Ramsay was awarded the 1904 Nobel Prize in Chemistry for discovery of a series of noble gases, including krypton.

Metric role

In 1960, an international agreement defined the meter in terms of wavelength of light emitted by the krypton-86 isotope (wavelength of 605.78 nanometers). This agreement replaced the longstanding standard meter located in Paris, which was a metal bar made of a platinum-iridium alloy (the bar was originally estimated to be one ten-millionth of a quadrant of the earth's polar circumference), and was itself replaced by a definition based on the speed of light — a fundamental physical constant. In October 1983, the Bureau International des Poids et Mesures (International Bureau of Weights and Measures) defined the meter as the distance that light travels in a vacuum during 1/299,792,458 s.5

Occurrence

The Earth has retained all of the noble gases that were present at its formation except for helium. Helium atoms are very light, and move fast enough to escape the Earth's gravity readily.6 Helium atoms present in the atmosphere result from the radioactive decay of thorium and uranium in the Earth. Krypton's concentration in the atmosphere is about 1 ppm. It can be extracted from liquid air by fractional distillation.7 The amount of krypton in space is uncertain, as is the amount is derived from the meteoric activity and that from solar winds. The first measurements suggest an overabundance of krypton in space.8

Compounds

Like the other noble gases, krypton is chemically unreactive. However, following the first successful synthesis of xenon compounds in 1962, synthesis of krypton difluoride (KrF2) was reported in 1963.9 In the same year, XeF4 was reported by Grosse, et al.,10 but was subsequently shown to be a mistaken identification.11 There are also unverified reports of a barium salt of a krypton oxoacid.12 ArKr+ and KrH+ molecule-ions have been investigated and there is evidence for KrXe or KrXe+.13

Compounds with krypton bonded to atoms other than fluorine have also been discovered. The reaction of KrF2 with B(OTeF5)3 produces an unstable compound, Kr(OTeF5)2, that contains a krypton-oxygen bond. A krypton-nitrogen bond is found in the cation [HC≡N–Kr–F]+, produced by the reaction of KrF2 with [HC≡NH]+[AsF−6 below −50 °C.1415

At the University of Helsinki in Finland, HKrCN and HKrC≡CH (krypton hydride-cyanide and hydrokryptoacetylene) were stable up to 40 K.9

Isotopes Main article: Isotopes of krypton

Naturally occurring krypton is made of six stable isotopes. In addition, about thirty unstable isotopes and isomers are known.16 81Kr, the product of atmospheric reactions is produced with the other naturally occurring isotopes of krypton. Being radioactive it has a half-life of 230,000 years. Krypton is highly volatile when it is near surface waters but 81Kr has been used for dating old (50,000 - 800,000 year) groundwater.17

85Kr is an inert radioactive noble gas with a half-life of 10.76 years. It is produced by the fission of uranium and plutonium, such as in nuclear bomb testing and nuclear reactors. 85Kr is released during the reprocessing of fuel rods from nuclear reactors. Concentrations at the North Pole are 30% higher than at the South Pole as most nuclear reactors are in the northern hemisphere.18

Applications Krypton gas discarge tube

Krypton's multiple emission lines make ionized krypton gas discharges appear whitish, which in turn makes krypton-based bulbs useful in photography as a brilliant white light source. Krypton is thus used in some types of photographic flashes used in high speed photography. Krypton gas is also combined with other gases to make luminous signs that glow with a bright greenish-yellow light.19

Krypton mixes with argon as the fill gas of energy saving fluorescent lamps. This reduces their power consumption. Unfortunately this also reduces their light output and raises their cost.20 Krypton costs about 100 times as much as argon. Krypton (along with xenon) is also used to fill incandescent lamps to reduce filament evaporation and allow higher operating temperatures to be used for the filament.21 A brighter light results which contains more blue than conventional lamps.

Krypton's white discharge is often used to good effect in colored gas discharge tubes, which are then simply painted or stained in other ways to allow the desired color (for example, "neon" type advertising signs where the letters appear in differing colors, are often entirely krypton-based). Krypton is also capable of much higher light power density than neon in the red spectral line region, and for this reason, red lasers for high-power laser light-shows are often krypton lasers with mirrors which select out the red spectral line for laser amplification and emission, rather than the more familiar helium-neon variety, which could never practically achieve the multi-watt red laser light outputs needed for this application.22

Krypton has an important role in production and usage of the krypton fluoride laser. The laser has been important in the nuclear fusion energy research community in confinement experiments. The laser has high beam uniformity, short wavelength, and the ability to modify the spot size to track an imploding pellet.23

In experimental particle physics, liquid krypton is used to construct quasi-homogeneous electromagnetic calorimeters. A notable example is the calorimeter of the NA48 experiment at CERN containing about 27 tons of liquid krypton. This usage is rare, since the cheaper liquid argon is typically used. The advantage of krypton over argon is a small Molière radius of 4.7 cm, which allows for excellent spatial resolution and low degree of overlapping. The other parameters relevant for calorimetry application are: radiation length of X0=4.7 cm, density of 2.4 g/cm3.

The sealed spark gap assemblies contained in ignition exciters used in some older jet engines contain a very small amount of Krypton-85 to obtain consistent ionization levels and uniform operation.

Krypton-83 has application in magnetic resonance imaging (MRI) for imaging airways. In particular, it may be used to distinguish between hydrophobic and hydrophilic surfaces containing an airway.24

Although xenon has potential for use in computed tomography (CT) to assess regional ventilation, its anesthetic properties limit its fraction in the breathing gas to 35%. The use of a breathing mixture containing 30% xenon and 30% krypton is comparable in effectiveness for CT to a 40% xenon fraction, while avoiding the unwanted effects of a high fraction xenon gas.25

Precautions

Krypton is considered to be a non-toxic asphyxiant.26 Krypton has a narcotic potency seven times greater than air, so breathing a gas containing 50% krypton and 50% air would cause narcosis similar to breathing air at four times atmospheric pressure. This would be comparable to scuba diving at a depth of 30 m (100 ft) (see nitrogen narcosis) and potentially could affect anyone breathing it. Nevertheless, that mixture would contain only 10% oxygen and hypoxia would be a greater concern.

References ^ Magnetic susceptibility of the elements and inorganic compounds, in Handbook of Chemistry and Physics 81st edition, CRC press. ^ "Spectra of Gas Discharges". http://astro.u-strasbg.fr/~koppen/discharge/. ^ "Krypton". Argonne National Laboratory, EVS. 2005. http://www.ead.anl.gov/pub/doc/krypton.pdf. Retrieved 2007-03-17. ^ William Ramsay, Morris W. Travers (1898). "On a New Constituent of Atmospheric Air". Proceedings of the Royal Society of London 63: 405–408. doi:10.1098/rspl.1898.0051. ^ Gibbs, Philip (1997). "How is the speed of light measured?". Department of Mathematics, University of California. http://math.ucr.edu/home/baez/physics/Relativity/SpeedOfLight/measure_c.html. Retrieved 2007-03-19. ^ Escape of Gases from the Atmosphere ^ "How Products are Made: Krypton". http://www.madehow.com/Volume-4/Krypton.html. Retrieved 2006-07-02. ^ Cardelli, Jason A.; Meyer, David M. (1996). "The Abundance of Interstellar Krypton". The Astrophysical Journal Letters. The American Astronomical Society. pp. L57–L60. http://www.journals.uchicago.edu/doi/full/10.1086/310513. Retrieved 2007-04-05. ^ a b Bartlett, Neil (2003). "The Noble Gases". Chemical & Engineering News. http://pubs.acs.org/cen/80th/noblegases.html. Retrieved 2006-07-02. ^ Grosse, A. V.; Kirshenbaum, A. D.; Streng, A. G.; Streng, L. V. (1963). "Krypton Tetrafluoride: Preparation and Some Properties". Science 139 (3559): 1047-1048. doi:10.1126/science.139.3559.1047. ^ Prusakov, V. N.; Sokolov, V. B. (1971). "Krypton difluoride". Soviet Atomic Energy 31 (3): 990-999. doi:10.1007/BF01375764. ^ Streng, A.; Grosse, A. (1964). "Acid of Krypton and Its Barium Salt.". Science (New York, N.Y.) 143 (3603): 242–243. doi:10.1126/science.143.3603.242. PMID 17753149. ^ "Periodic Table of the Elements". Los Alamos National Laboratory's Chemistry Division. pp. 100–101. http://www.bu.edu/ehs/ih/pdf/periodic_table.pdf. Retrieved 2007-04-05. ^ John H. Holloway; Eric G. Hope (1998). A. G. Sykes. ed. Advances in Inorganic Chemistry. Academic Press. pp. 57. ISBN 012023646X. ^ Errol G. Lewars (2008). Modeling Marvels: Computational Anticipation of Novel Molecules. Springer. p. 68. ISBN 1402069723. http://books.google.com/books?id=whdw2qlXjD0C. ^ Lide, D. R., ed. (2005), CRC Handbook of Chemistry and Physics (86th ed.), Boca Raton (FL): CRC Press, ISBN 0-8493-0486-5 ^ Thonnard, Norbert; Larry D. MeKay, Theodore C. Labotka (31). "Development of Laser-Based Resonance Ionization Techniques for 81-Kr and 85-Kr Measurements in the Geosciences". University of Tennessee, Institute for Rare Isotope Measurements. pp. 4–7. http://www.osti.gov/bridge/servlets/purl/809813-0zMCV1/native/809813.pdf. Retrieved 2007-03-20. ^ "Resources on Isotopes". U.S. Geological Survey. http://wwwrcamnl.wr.usgs.gov/isoig/period/kr_iig.html. Retrieved 2007-03-20. ^ "Mercury in Lighting". Cape Cod Cooperative Extension. http://www.capecodextension.org/pdfs/Mercury%20Lighting.pdf. Retrieved 2007-03-20. ^ "Energy-saving" lamps ^ Properties, Applications and Uses of the "Rare Gases" Neon, Krypton and Xenon ^ "Laser Devices, Laser Shows and Effect" (PDF). http://www.gameops.com/content/pdf/laser_terms.pdf. Retrieved 2007-04-05. ^ Sethian, J.; M. Friedman, M.Myers. "Krypton Fluoride Laser Development for Inertial Fusion Energy". Plasma Physics Division, Naval Research Laboratory. pp. 1–8. http://aries.ucsd.edu/LIB/MEETINGS/IAEAIFECRP/PDF/Sethian.pdf. Retrieved 2007-03-20. ^ Pavlovskaya, GE; Cleveland, ZI; Stupic, KF; Basaraba, RJ; Meersmann, T (2005). "Hyperpolarized krypton-83 as a contrast agent for magnetic resonance imaging". Proceedings of the National Academy of Sciences U.S.A. 102 (51): 18275–9. doi:10.1073/pnas.0509419102. PMID 16344474. ^ Chon, D; Beck, KC; Simon, BA; Shikata, H; Saba, OI; Hoffman, EA (2007). "Effect of low-xenon and krypton supplementation on signal/noise of regional CT-based ventilation measurements". Journal of Applied Physiology 102 (4): 1535–44. doi:10.1152/japplphysiol.01235.2005. PMID 17122371. ^ Properties of Krypton Further reading "Krypton 85: a Review of the Literature and an Analysis of Radiation Hazards" By: William P. Kirk. External links Wikimedia Commons has media related to: Krypton Look up krypton in Wiktionary, the free dictionary. WebElements.com – Krypton Krypton Fluoride Lasers Computational Chemistry Wiki v • d • e Periodic table H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Uut Uuq Uup Uuh Uus Uuo Uue Ubn Ubu Ubb Alkali metals Alkaline earth metals Lanthanoids Actinoids Transition metals Other metals Metalloids Other nonmetals Halogens Noble gases

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